Phosphorous Ligands in Asymmetric Catalysis Synthesis and Applications by Armin Börner

Cover of: Phosphorous Ligands in Asymmetric Catalysis | Armin Börner

Published by Wiley-VCH .

Written in English

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Subjects:

  • Catalysis,
  • Organic chemistry,
  • Science / Chemistry / Organic,
  • Chemistry - Organic,
  • Science,
  • Science/Mathematics

Book details

The Physical Object
FormatHardcover
Number of Pages1546
ID Numbers
Open LibraryOL12767577M
ISBN 103527317465
ISBN 109783527317462

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(source: Nielsen Book Data) Summary With its list of contributors reading like a who's who, this is the ultimate standard reference on phosphorus in catalysis. Clearly divided into substance classes and spanning three volumes, it provides readers with an excellent introduction to the multitude of applications, backed by examples of optimal.

Phosphorus Ligands in Asymmetric Catalysis. Armin Börner (Editor) ISBN: pages. TRIVALENT PHOSPHOROUS LIGANDS IN METAL-CATALYZED REACTIONS reviews, book chapters and patents. He was awarded the departmental price for organic chemistry of the AdW, The Otto-Röhm price and the Descartes price of the European Union.

With its list of contributors reading like a whos who, this is the ultimate standard reference on phosphorus in catalysis. Clearly divided into substance classes and spanning three volumes, it provides readers with an excellent introduction to the multitude of applications, backed by examples of optimal solutions.

A definite must-have for all chemists working in synthetic Author: Armin Börner. An extensive treatment of the most important class of organic ligands for asymmetric catalysis, written by the who-is-who of top researchers in this field. Clearly divided into substance classes, this outstanding trio of books explain both general and specific methods of the synthesis of trivalent phosphorous compounds with relevance to Author: Armin Börner.

An extensive treatment of the most important class of organic ligands for asymmetric catalysis, written by the who-is-who of top researchers in this field.

Clearly divided into substance classes, this outstanding trio of books explain both general and specific methods of the synthesis of trivalent phosphorous compounds with relevance to.

Request PDF | Chiral Phosphorous Ligands in Asymmetric Catalysis | Several aspects of chiral P-ligands, such as theoretical background, synthesis, application, coordination chemistry, and. TY - CHAP. T1 - Chiral Phosphorous Ligands in Asymmetric Catalysis.

AU - Kégl, T. AU - Kollár, L. PY - /8/1. Y1 - /8/1. N2 - Several aspects of chiral P-ligands, such as theoretical Phosphorous Ligands in Asymmetric Catalysis book, synthesis, application, coordination chemistry, and asymmetric catalysis, have been reviewed during the past chapter aims to shed some more light on the various Cited by: 2.

The preparation of chiral compounds in enantiomerically pure form is a challenging goal in modern organic synthesis.

The use of chiral metal complex catalysis is a powerful, economically feasible tool for the preparation of optically active organic compounds on both laboratory and industrial scales.

In particular, the metals coordinated by one or more chiral phosphorus Cited by:   Phosphorus ligands in asymmetric catalysis; 3v. by Armin Borner.

Wiley-VCH pages $ Hardcover QD Phosphorous ligands (or P-ligands) occupy a unique position in asymmetric catalysis because their special ligating properties help them form stable complexes with those metals that are catalytically active in several.

Enantioselective synthesis, also called asymmetric synthesis, is a form of chemical synthesis. It is defined by IUPAC as: a chemical reaction (or reaction sequence) in which one or more new elements of chirality are formed in a substrate molecule and which produces the stereoisomeric (enantiomeric or diastereoisomeric) products in unequal amounts.

Phosphorous Ligands in Asymmetric Catalysis book more simply: it is the. ISBN: OCLC Number: Description: 3 volumes (xl, pages): illustrations (some color) ; 25 cm: Contents: Introduction TRIVALENT PHOSPHOROUS LIGANDS IN METAL-CATALYZED REACTIONS Chiral Monodentate Phosphorous Ligands Chiral Bidentate Phosphorous Ligands Chiral Polyphosphorous Ligands.

Phosphine ligands are phosphines, compound of the formula PRR'R" (R, R', R" = H, alkyl, aryl, etc) that are used as ligands in metal complexes, often related to organometallic chemistry and homogeneous compounds are also used in other areas of chemistry. This book will provide helpful advice as to the accessibility of ligands as well as their synthesis, thereby allowing researchers to make a more informed choice.

Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis is an essential overview of this important class of catalysts for academic and industrial researchers working in Author: Kamer, Paul (Paul C.

J.). Download Citation | On Jan 1,J. Wassenaar and others published Phosphorus Ligands in Asymmetric Catalysis, Vols. I–III | Find, read and cite all the research you need on ResearchGateAuthor: Jeroen Wassenaar. A library of new fine-tunable monodentate phosphite and phosphoramidite ligands based on chiral biphenol has been designed and developed.

These monodentate phosphorus ligands have exhibited excellent enantioselectivity in the Pd-catalyzed asymmetric allylic alkylation, Rh-catalyzed asymmetric hydrogenation and hydroformylation, and Cu-catalyzed conjugate Cited by: 5. Asymmetric Catalysis in Ionic Liquids: Easy Recycling of Catalyst and Improvement of Catalytic Performances Choong Eui Song Chap DOI: /bkch Publication Date (Print): July 4, E-mail: @ Dedicated to Prof.

Lutz F. Tietze on the occasion of his 65th birthday Abstract We describe our recent achievements in the synthesis of chiral phosphorous ligands and their application in catalytic asymmetric hydrogenation reactions. Special attention is given to theCited by: 2.

Methodologies in Asymmetric Catalysis is a useful reference book for scientists working in the field of asymmetric catalysis. Rating: (not yet rated) 0 with reviews - Be the first. Phosphorous-containing molecules are of great interest especially as ligands for catalysis.

In particular in the case of thiahelicenes, the introduction of this type of substituents in one or both of the 2- and positions is important for preparing chiral helical phosphorous ligands with potential applications in organo- and organometallic.

Synthesis and applications of a new class of phosphorus donor ligands for asymmetric catalysis. Heather Tye, Donald Smyth, Authors contributing to RSC publications (journal articles, books or book chapters) do not need to formally request permission to reproduce material contained in this article provided that the correct acknowledgement.

Asymmetric Catalysis Privileged Ligands and Complexes Features include: BINAP/SEGPHOS® Ligands and Complexes Solvias® Ligand Portfolio for Enantioselective Hydrogenation DuPhos and BPE Phospholane Ligands and Complexes Vol.

8, No. 2 BINAP, a powerful ligand for asymmetric catalysis 1 5/15/ AM. From the contents: Robert H Crabtree: Introduction and History.

- Montserrat Diéguez, Oscar Pàmies and Carmen Claver: Iridium-catalysed hydrogenation using phosphorous ligands. - David H. Woodmansee and Andreas Pfaltz: Iridium Catalyzed Asymmetric Hydrogenation of Olefins with Chiral N,P and C,N : Springer. 7) The methine protons in 2a and 2e appear as quartets at δ and ppm respectively.

Their cis-diastereoisomers have corresponding resonances at δ and ppm (multiplet and sextet respectively).The same pattern is repeated in a derivative of 2a containing a 2-pyrollidylethyl group in the nitrogen atom, the relative configuration in which, like 2e, has been confirmed by Cited by: Developing Chiral Ligands for Asymmetric HydrogenationCited by: Phosphorus Ligand Effects in Homogeneous Catalysis and Rational Catalyst Design Jason A.

Gillespie EaStCHEM, School of Chemistry, University of St Andrews Purdie Building, North Haugh St Andrews, Fife KY16 9ST United KingdomCited by: From the contents: Robert H Crabtree: Introduction and History.

- Montserrat Diéguez, Oscar Pàmies and Carmen Claver: Iridium-catalysed hydrogenation using phosphorous ligands. - David H. Woodmansee and Andreas Pfaltz: Iridium Catalyzed Asymmetric Hydrogenation of Olefins with Chiral N,P and C,N Ligands. - Ourida Saidi and Jonathan M J Williams: Iridium-catalyzed.

This book addresses the design and synthesis of a comprehensive compilation of phosphorous(III) ligands for homogeneous catalysis. It not only focuses on the well-known traditional ligands that have been explored by catalysis researchers, but also includes promising ligand types that have traditionally been ignored mainly because of their.

From the contents: Robert H Crabtree: Introduction and History. - Montserrat Diéguez, Oscar Pàmies and Carmen Claver: Iridium-catalysed hydrogenation using phosphorous ligands.

- David H. Woodmansee and Andreas Pfaltz: Iridium Catalyzed Asymmetric Hydrogenation of Olefins with Chiral N,P and C,N. Summary reported for both phosphinites and phosphonites. The main conclusions that can be derived from this survey are i) that phosphines are still and by far the most studied of all phosphorus ligands, with the focus nowadays on the development of chiral ligands for asymmetric catalysis, ii) that new phosphites and their transition metal complexes continue to create.

The data published during the last five years on the application of chiral derivatives of phosphorous acid in coordination chemistry and enantioselective catalysis are summarised and discussed.

The effect of the nature of these ligands on the structure of metal complexes and on the efficiency of catalytic or. Each chapter of Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences have been carefully selected by the editors in order to represent a state-of-the-art overview of how phosphorus chemistry can provide solutions in various.

chemistry, homogeneous catalysis, dendrimers, theoretical calculations, materials science, and medicinal chemistry with a special focus on the chemistry of phosphorus compounds.

Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences is of interest to a general readership ranging from advanced. Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis is an essential overview of this important class of catalysts for academic and industrial researchers working in catalyst development, organometallic and synthetic : $ From the contents: Robert H Crabtree: Introduction and History.

- Montserrat Diéguez, Oscar Pàmies and Carmen Claver: Iridium-catalysed hydrogenation using phosphorous ligands. - David H. Woodmansee and Andreas Pfaltz: Iridium Catalyzed Asymmetric Hydrogenation of Olefins with Chiral N,P and C,N Ligands.

Methodologies in Asymmetric Catalysis brings together leading scientists who have made major contributions to the field of asymmetric catalysis. This book assembles several new methodologies that are interdisciplinary by nature, incorporating organic synthesis, coordination chemistry, auto-catalysis, homogeneous and heterogeneous catalysis, kinetics and.

From the contents: Robert H Crabtree: Introduction and History. - Montserrat Diéguez, Oscar P mies and Carmen Claver: Iridium-catalysed hydrogenation using phosphorous ligands. - David H. Woodmansee and Andreas Pfaltz: Iridium Catalyzed Asymmetric Hydrogenation of Olefins with Chiral N,P and C,N Ligands.

quent ligands design for asymmetric catalysis. In recent years new nonsymmetric nonsymmetric ligands that are more effective than their C. counterparts have been reported. The first chapters of this book are dedicated to ‘‘rational’’ ligand design, which is cri- symmetric multidentate ligands bearing phosphorous, nitrogen.

Experimental. Preparation of (2S) Ethyl 2-(tetrahydro-2H-pyranyloxy) propanoate 7. (S)-Ethyl lactate 6 ( g, mmol) and dihydropyran (30 ml) were dissolved in DCM ( ml) and the resulting colourless solution was treated with PPTS ( g) at 0 solution was stirred under argon for 24 hours and then quenched by the addition of saturated sodium bicarbonate.

Asymmetric catalysis with transition-metal complexes is the basis for a vast array of stereoselective transformations and has changed the face of modern synthetic chemistry. Key to this success has been the design of chiral ligands to control the regio- diastereo- and enantioselectivity.

Phosphoramidites have emerged as a highly versatile and Cited by: Phosphorus Ligands in Asymmetric Catalysis 作者: Börner, Armin 编 出版年: 页数: 定价: 元 ISBN: 豆瓣评分. Rosenthal, Uwe ChemCatChem,12, PNPN-H in Comparison to other PNP, PNPN and NPNPN Ligands for the Chromium Catalyzed Selective Ethylene Oligomerization.asymmetric catalysis is a highly active field of research 8 that concentrates especially, on chiral P,P and P,N-ligands, since this type of ligands plays a wide role in transition-metal-catalyzed asymmetric Size: 1MB.A rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to substituted maleimides has been described.

The regioselectivity in this reaction is controlled by the choice of ligand (dienes or bisphosphines), and 1,4-adducts with a quaternary stereocenter can be obtained with high regio- and enantioselectivity by the use of (R) by:

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